Molecular modelling of supramolecular one dimensional polymers

Supramolecular one - dimensional objects

Preparing polymer-like materials through supramolecular chemistry is an area of growing interest, yet full understanding of how non-covalent forces may be used to prepare such materials is lacking and as a result the success of these strategies is often serendipitous. Recent examples of discrete one-dimensional supramolecular fibers employing the most important types of non-covalent interaction...

Supramolecular One-Dimensional n/p-Nanofibers

Currently, there is a broad interest in the control over creating ordered electroactive nanostructures, in which electron donors and acceptors are organized at similar length scales. In this article, a simple and efficient procedure is reported en-route towards the construction of 1D arrays of crystalline pristine C60 and phenyl-C61-butyric acid methyl ester (PCBM) coated onto supramolecular fi...

Metallo-supramolecular cyclic polymers.

Cyclic brush polymers represent an exciting new macromolecular topology. For the first time, this new topology has been combined with metallo-supramolecular interactions to construct novel cyclic brush polymers. Here, ring-expansion metathesis polymerization was used to synthesize a universal cyclic template with a polynorbornene backbone, which was further modified with the metal-chelating syn...

One-dimensional palladium wires: influence of molecular changes on supramolecular structure.

Nanostructured materials based on one-dimensional (1D) metal wires are of potential utility; however, to date, there is a lack of synthetic methods that allow for variation of structure and therefore properties. Here we report the use of molecular control elements to alter the solid-state structures of 1D palladium wires, including Pd-Pd bond distances and the porosity of the supramolecular fra...

Multiple Hydrogen-Bonded Supramolecular Polymers